JEE Advance - Chemistry (1986 - No. 10)
Explanation
To solve this problem, we need to understand the relationship between the energy of a photon and its wavelength. The energy of a photon (E) can be calculated using the equation:
$$E = \frac{hc}{\lambda}$$
where:
- $E$ is the energy of the photon,
- $h$ is Planck's constant ($6.626 \times 10^{-34} \, \text{J s}$),
- $c$ is the speed of light in vacuum ($3.0 \times 10^8 \, \text{m/s}$),
- $\lambda$ is the wavelength of the photon.
Let's denote the energy of a photon with a wavelength of 2000Å as $E_1$, and the energy of a photon with a wavelength of 4000Å as $E_2$. We need to find the ratio $\frac{E_1}{E_2}$.
First, convert wavelengths from Ångströms to meters, since the constants are in SI units:
1Å = $10^{-10}$ meters.
- So, 2000Å = $2000 \times 10^{-10}$ meters = $2 \times 10^{-7}$ meters.
- And 4000Å = $4000 \times 10^{-10}$ meters = $4 \times 10^{-7}$ meters.
Next, we can substitute the values into the energy equation for both $E_1$ and $E_2$ and then find their ratio:
$$E_1 = \frac{hc}{\lambda_1} = \frac{6.626 \times 10^{-34} \times 3.0 \times 10^8}{2 \times 10^{-7}}$$
$$E_2 = \frac{hc}{\lambda_2} = \frac{6.626 \times 10^{-34} \times 3.0 \times 10^8}{4 \times 10^{-7}}$$
Now, let's find the ratio $\frac{E_1}{E_2}$:
$$\frac{E_1}{E_2} = \frac{\frac{6.626 \times 10^{-34} \times 3.0 \times 10^8}{2 \times 10^{-7}}}{\frac{6.626 \times 10^{-34} \times 3.0 \times 10^8}{4 \times 10^{-7}}} = \frac{4 \times 10^{-7}}{2 \times 10^{-7}} = 2$$
Therefore, the ratio of the energy of a photon of 2000Å wavelength to that of a 4000Å radiation is 2. Hence, the correct answer is:
Option D: 2
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