JEE Advance - Chemistry (1985 - No. 17)
Rate of diffusion of a gas is
directly proportional to its density
directly proportional to the square root of its molecular weight
inversely proportional to the square root of its molecular weight.
directly proportional to its molecular weight
Explanation
Diffusion of a gas is described by Graham's Law, which states that the rate of diffusion (or effusion) of a gas is inversely proportional to the square root of its molecular mass. This law is mathematically represented as:
$$ \text{Rate of diffusion} \propto \frac{1}{\sqrt{\text{Molecular Mass}}} $$
Given this information, let's analyze the options:
- Option A: Directly proportional to its density - This is incorrect because density and molecular mass are related, but the rate of diffusion is inversely related to the square root of molecular mass, not directly proportional to density.
- Option B: Directly proportional to the square root of its molecular weight - This is incorrect. The relationship is inverse; the rate decreases as the molecular weight increases.
- Option C: Inversely proportional to the square root of its molecular weight - This is the correct option. As molecular mass increases, the rate of diffusion decreases in proportion to the inverse of the square root of the molecular mass.
- Option D: Directly proportional to its molecular weight - This is incorrect as it contradicts the principle of Graham's Law.
Thus, the correct answer is Option C: inversely proportional to the square root of its molecular weight.
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