JEE Advance - Chemistry (1985 - No. 12)
Explanation
The statement "SnCl2 is a non-linear molecule" is TRUE.
To understand why SnCl2 (Tin(II) chloride) is a non-linear molecule, we need to look at its molecular geometry. Tin (Sn) is the central atom and it has a lone pair of electrons along with two bonding pairs of electrons with the chlorine (Cl) atoms. This creates a V-shaped or bent molecular geometry.
According to the Valence Shell Electron Pair Repulsion (VSEPR) theory, the lone pair of electrons on the tin atom will repel the bonding pairs, causing the molecule to take on a shape that minimizes repulsion. Therefore, the electron geometry of SnCl2 is trigonal planar, but because of the lone pair, the molecular shape is bent.
The bond angle in a bent molecule like SnCl2 deviates from the typical 180 degrees and is approximately 120 degrees. This bent shape confirms that SnCl2 is non-linear.
Hence, the correct answer is:
Option A: TRUE
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