JEE Advance - Chemistry (1983 - No. 10)
Explanation
The absorption of hydrogen by palladium is commonly known as "occlusion".
Let's dive a bit deeper into this concept:
Palladium has a unique ability to absorb large quantities of hydrogen gas. When hydrogen gas comes into contact with palladium, the hydrogen molecules dissociate into individual hydrogen atoms. These atoms are then absorbed into the interstitial spaces between the palladium atoms in its crystal lattice. This process of hydrogen absorption is not merely a physical process but also involves some chemical interactions at the atomic level.
The term "occlusion" refers to this specific phenomenon. The absorbed hydrogen can be released again upon heating or by applying a vacuum, making palladium-hydrogen systems very useful in various applications, such as hydrogen storage, purification, and sensors.
To understand this interaction more quantitatively, consider the solubility of hydrogen in palladium which can be described by the Sieverts' law:
$$ C_H = K \cdot \sqrt{P_H} $$
Where:
- $$C_H$$ is the concentration of hydrogen in palladium.
- $$K$$ is the Sieverts' constant.
- $$P_H$$ is the partial pressure of hydrogen gas.
This relationship shows that the concentration of absorbed hydrogen is proportional to the square root of the hydrogen gas pressure.
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