JEE Advance - Chemistry (1981 - No. 3)

1 mole of N2H4 loses 10 moles of electrons to form a new compound Y. assuming that all nitrogen appears in the new compound , what is the oxidation state of nitrogen in Y ? (there is no change in the oxidation state of hydrogen)
-1
-3
+3
+5

Explanation

First, let's understand the given information. We have hydrazine (N2H4) losing 10 moles of electrons to form a new compound (Y). In this context, the oxidation state of hydrogen remains unchanged, which is +1.

To solve this problem, we should follow these steps:

1. Determine the initial oxidation state of nitrogen in N2H4.

In N2H4, hydrogen is in the +1 oxidation state. Since the molecule is neutral, the sum of oxidation states must equal 0. We can express this relationship as:

2x + 4(+1) = 0

Where x is the oxidation state of one nitrogen atom. This can be rearranged to find x:

2x = -4

x = -2

So, the initial oxidation state of nitrogen in N2H4 is -2.

2. Determine the change in oxidation state of nitrogen.

When 1 mole of N2H4 loses 10 moles of electrons, the nitrogen atoms undergo oxidation, meaning their oxidation state increases. The loss of 10 electrons per mole of N2H4 means that there's an increase of 5 oxidation states per nitrogen atom, because there are 2 nitrogen atoms in each molecule of N2H4.

3. Calculate the final oxidation state of nitrogen.

The initial oxidation state of nitrogen is -2. With the loss of electrons, the oxidation state increases by 5 for each nitrogen atom:

Final oxidation state = Initial oxidation state + Increase in oxidation state

Final oxidation state of nitrogen = -2 + 5 = +3

Therefore, the oxidation state of nitrogen in the new compound Y is +3.

The correct answer is Option C: +3.

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