JEE Advance - Chemistry (1981 - No. 10)

Equal weights of methane and oxygen are mixed in an empty container at 25oC. The fraction of the total pressure exerted by oxygen is
1/3
1/2
2/3
$${1 \over 3} \times {{273} \over {298}}$$

Explanation

To find the fraction of the total pressure exerted by oxygen, we need to consider the mole fractions of methane (CH4) and oxygen (O2) in the mixture. Here are the steps to solve this problem:

1. Let us assume equal weights, say 'W' grams, of methane and oxygen are mixed.

2. The molecular weights of methane and oxygen are 16 g/mol and 32 g/mol, respectively. The moles of methane (nCH4) and moles of oxygen (nO2) in the mixture are then calculated as follows:

  • $$ n_{CH_4} = \frac{\text{Mass of CH}_4}{\text{Molar mass of CH}_4} = \frac{W}{16} \text{ moles} $$
  • $$ n_{O_2} = \frac{\text{Mass of O}_2}{\text{Molar mass of O}_2} = \frac{W}{32} \text{ moles} $$

3. For W grams of each gas, ratio of moles becomes:

  • $$ \text{The mole ratio of CH}_4 \text{ to O}_2 = \frac{W/16}{W/32} = \frac{32}{16} = 2 \text{ to } 1 $$

4. With 2 moles of CH4 for every 1 mole of O2, the total moles in the mixture are 3 moles (2 moles CH4 + 1 mole O2).

5. According to Dalton's law of partial pressures, the total pressure P in the container is the sum of the partial pressures of the components. Each component's partial pressure is proportional to its mole fraction:

  • Mole fraction of O2, $$ X_{O_2} = \frac{n_{O_2}}{n_{total}} = \frac{1}{3} $$

6. Hence, the fraction of the total pressure exerted by oxygen would be:

$$ \text{Fraction exerted by O}_2 = X_{O_2} = \frac{1}{3} $$

Therefore, the correct answer is: Option A - 1/3.

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