JEE MAIN - Chemistry (2025 - 7th April Evening Shift - No. 18)
The extra stability of half-filled subshell is due to :
(A) Symmetrical distribution of electrons
(B) Smaller coulombic repulsion energy
(C) The presence of electrons with the same spin in non-degenerate orbitals
(D) Larger exchange energy
(E) Relatively smaller shielding of electrons by one another
Indentify the correct statements :
Explanation
The enhanced stability of a half-filled subshell is attributed to the following factors:
Symmetrical Distribution of Electrons: Electrons are evenly distributed across the available orbitals, leading to a balanced and stable arrangement.
Large Exchange Energy: The energy due to the exchange of electrons with parallel spins among degenerate orbitals is maximized, contributing to increased stability.
Smaller Coulombic Repulsion: The repulsion between electrons is minimized in a half-filled configuration, reducing the overall energy of the subshell.
Smaller Shielding of Electrons: In a half-filled subshell, electrons are more exposed to the nuclear charge, as there is less shielding effect from other electrons, enhancing stability.
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