JEE MAIN - Chemistry (2025 - 7th April Evening Shift - No. 18)

The extra stability of half-filled subshell is due to :

(A) Symmetrical distribution of electrons

(B) Smaller coulombic repulsion energy

(C) The presence of electrons with the same spin in non-degenerate orbitals

(D) Larger exchange energy

(E) Relatively smaller shielding of electrons by one another

Indentify the correct statements :

(B), (D) and (E) only
$(A),(B),(D)$ and (E) only
(B), (C) and (D) only
$(A),(B)$ and (D) only

Explanation

The enhanced stability of a half-filled subshell is attributed to the following factors:

Symmetrical Distribution of Electrons: Electrons are evenly distributed across the available orbitals, leading to a balanced and stable arrangement.

Large Exchange Energy: The energy due to the exchange of electrons with parallel spins among degenerate orbitals is maximized, contributing to increased stability.

Smaller Coulombic Repulsion: The repulsion between electrons is minimized in a half-filled configuration, reducing the overall energy of the subshell.

Smaller Shielding of Electrons: In a half-filled subshell, electrons are more exposed to the nuclear charge, as there is less shielding effect from other electrons, enhancing stability.

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