JEE MAIN - Chemistry (2025 - 4th April Evening Shift - No. 6)

Consider the ground state of chromium atom $(Z=24)$. How many electrons are with Azimuthal quantum number $l=1$ and $l=2$ respectively ?
16 and 5
12 and 5
12 and 4
16 and 4

Explanation

The ground state electron configuration of chromium (Cr, $ Z = 24 $) is:

$$ \text{Cr: } [\text{Ar}]\,3d^5\,4s^1 $$

Let's break down the configuration:

The noble gas core $[\text{Ar}]$ represents:

$1s^2$ (with $l=0$)

$2s^2$ (with $l=0$)

$2p^6$ (with $l=1$)

$3s^2$ (with $l=0$)

$3p^6$ (with $l=1$)

Electrons with azimuthal quantum number $l = 1$ are found in $p$ orbitals:

$2p^6$: 6 electrons

$3p^6$: 6 electrons

Total $p$-electrons: $6 + 6 = 12$.

Electrons with azimuthal quantum number $l = 2$ are found in $d$ orbitals:

$3d^5$: 5 electrons

Thus, there are 12 electrons with $l = 1$ and 5 electrons with $l = 2$.

The correct option is Option B.

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