JEE MAIN - Chemistry (2025 - 2nd April Morning Shift - No. 21)
For the reaction A $\to$ products.
The concentration of A at 10 minutes is _________ $\times 10^{-3} \mathrm{~mol} \mathrm{~L}^{-1}$ (nearest integer). The reaction was started with $2.5 \mathrm{~mol} \mathrm{~L}^{-1}$ of A .
Explanation
Order of Reaction:
Since $ t_{1/2} \propto [A]_0 $, the reaction follows a zero-order kinetics.
Half-life Equation for Zero-order Reaction:
The half-life ($ t_{1/2} $) is calculated as:
$ t_{1/2} = \frac{[A]_0}{2K} $
Given the slope from the graph is $76.92$, which equals $\frac{1}{2K}$. This implies:
$ K = \frac{1}{2 \times 76.92} $
Concentration of A at 10 Minutes:
Apply the zero-order kinetics equation:
$ [A]_{10} = -Kt + [A]_0 $
Substituting the values:
$ [A]_{10} = -\left(\frac{1}{2 \times 76.92}\right) \times 10 + 2.5 = 2.435 \ \text{mol L}^{-1} $
Final Concentration:
Convert to scientific notation:
$ [A]_{10} = 2435 \times 10^{-3} \ \text{mol L}^{-1} $
Thus, the concentration of A at 10 minutes is approximately $ 2435 \times 10^{-3} \ \text{mol L}^{-1} $.
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