JEE MAIN - Chemistry (2025 - 2nd April Morning Shift - No. 19)

The property/properties that show irregularity in first four elements of group-17 is/are

(A) Covalent radius

(B) Electron affinity

(C) Ionic radius

(D) First ionization energy

Choose the correct answer from the options given below :

A, B, C and D
A and C only
B only
B and D only

Explanation

The order of first four elements of group-17 are as follows.

$$\mathrm{F}<\mathrm{Cl}<\mathrm{Br}<\mathrm{I} \text { (Covalent radius) }$$

$\mathrm{Cl}>\mathrm{F}>\mathrm{Br}>\mathrm{I}$ (Electron affinity)

$\mathrm{F}<\mathrm{Cl}^{-}<\mathrm{Br}^{-}<\mathrm{I}$ (Ionic radius)

$\mathrm{F}>\mathrm{Cl}>\mathrm{Br}>\mathrm{I}$ ( $\mathrm{I}^{\mathrm{st}}$ ionization energy)

Electron affinity order is irregular.

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