JEE MAIN - Chemistry (2025 - 29th January Morning Shift - No. 5)
Explanation
$$ C_P = \frac{5}{2} R \qquad \text{and} \qquad C_V = \frac{3}{2} R $$
For a constant pressure process, the heat added is related to the temperature change by
$$ Q = n C_P \Delta T. $$
Given that
$$Q = 500 \, \text{J},$$
$$n = 0.5 \, \text{mol},$$
$$R = 8.3 \, \text{J K}^{-1} \text{mol}^{-1},$$
and the initial temperature $$T_i = 298 \, \text{K},$$
we first calculate $$C_P$$:
$$ C_P = \frac{5}{2} \times 8.3 = 20.75 \, \text{J K}^{-1} \text{mol}^{-1}. $$
Next, the temperature change is
$$ \Delta T = \frac{Q}{n C_P} = \frac{500 \, \text{J}}{0.5 \, \text{mol} \times 20.75 \, \text{J K}^{-1} \text{mol}^{-1}} \approx 48.2 \, \text{K}. $$
So, the final temperature is
$$ T_f = T_i + \Delta T \approx 298 \, \text{K} + 48.2 \, \text{K} \approx 346.2 \, \text{K}. $$
Rounded to the nearest units provided in the options, this is approximately $$348 \, \text{K}.$$
The change in internal energy is determined by
$$ \Delta U = n C_V \Delta T, $$
where
$$ C_V = \frac{3}{2} R = \frac{3}{2} \times 8.3 = 12.45 \, \text{J K}^{-1} \text{mol}^{-1}. $$
Then,
$$ \Delta U = 0.5 \, \text{mol} \times 12.45 \, \text{J K}^{-1} \text{mol}^{-1} \times 48.2 \, \text{K} \approx 300 \, \text{J}. $$
Thus, the final answers are:
Final temperature: approximately $$348 \, \text{K}$$
Change in internal energy: approximately $$300 \, \text{J}$$
These results correspond to Option B.
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