JEE MAIN - Chemistry (2025 - 28th January Morning Shift - No. 14)

Consider ' n ' is the number of lone pair of electrons present in the equatorial position of the most stable structure of $\mathrm{ClF}_3$. The ions from the following with ' n ' number of unpaired electrons are

A. $\mathrm{V}^{3+}$

B. $\mathrm{Ti}^{3+}$

C. $\mathrm{Cu}^{2+}$

D. $\mathrm{Ni}^{2+}$

E. $\mathrm{Ti}^{2+}$

Choose the correct answer from the options given below:

B and D Only
A, D and E Only
B and C Only
A and C Only

Explanation

JEE Main 2025 (Online) 28th January Morning Shift Chemistry - Chemical Bonding & Molecular Structure Question 2 English Explanation

$\mathrm{n}=2($ No of lone pair present in equitorial plane)

$$\begin{array}{lc} & \text { (Unpaired } \mathrm{e}^{-} \text {) } \\ \text { (A) } \mathrm{V}^{+3}:[\mathrm{Ar}] 3 \mathrm{~d}^2 & 2 \\ \text { (B) } \mathrm{Ti}^{3+}:[\mathrm{Ar}] 3 \mathrm{~d}^1 & 1 \\ \text { (C) } \mathrm{Cu}^{+2}:[\mathrm{Ar}] 3 \mathrm{~d}^9 & 1 \\ \text { (D) } \mathrm{Ni}^{+2}:[\mathrm{Ar}] 3 \mathrm{~d}^8 & 2 \\ \text { (E) } \mathrm{Ti}^{+2}:[\mathrm{Ar}] 3 \mathrm{~d}^2 & 2 \end{array}$$

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