JEE MAIN - Chemistry (2025 - 22nd January Evening Shift - No. 23)

Niobium $(\mathrm{Nb})$ and ruthenium $(\mathrm{Ru})$ have " $x$ " and " $y$ " number of electrons in their respective 4 d orbitals. The value of $x+y$ is __________.
Answer
11

Explanation

We need to determine the number of electrons each element has in its 4d orbitals and then add them together.


1. Niobium $\mathrm{(Nb, Z = 41)}$

The ground‐state electronic configuration of niobium is:

$ [\mathrm{Kr}]\,4d^4\,5s^1. $

Hence, Niobium has 4 electrons in its 4d orbitals.


2. Ruthenium $\mathrm{(Ru, Z = 44)}$

The ground‐state electronic configuration of ruthenium is:

$ [\mathrm{Kr}]\,4d^7\,5s^1. $

Hence, Ruthenium has 7 electrons in its 4d orbitals.


3. Sum of 4d Electrons

$ x \;=\; 4 \quad (\text{for Nb}), \quad y \;=\; 7 \quad (\text{for Ru}). $

Therefore,

$ x + y \;=\; 4 \;+\; 7 \;=\; 11. $


Answer: 11

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