JEE MAIN - Chemistry (2025 - 22nd January Evening Shift - No. 19)
Given below are two statements :
Statement (I) : A spectral line will be observed for a $2 p_x \rightarrow 2 p_y$ transition.
Statement (II) : $2 \mathrm{p}_x$ and $2 \mathrm{p}_y$ are degenerate orbitals.
In the light of the above statements, choose the correct answer from the options given below :
Explanation
Let us analyze the two statements in the context of atomic orbitals and electronic transitions:
Statement (I)
“A spectral line will be observed for a $ 2 p_x \rightarrow 2 p_y $ transition.”
For an emission (or absorption) line to be observed, there must be a difference in energy between the initial and final states.
In a typical hydrogen-like or many-electron atom (without additional external fields or splitting effects), the three $2p$ orbitals ($2 p_x$, $2 p_y$, $2 p_z$) are degenerate—i.e., they all have the same energy.
Consequently, a transition from $2 p_x$ to $2 p_y$ (both having the same energy) would involve no energy change. Hence, no photon is emitted or absorbed for this “transition.” So you would not observe a spectral line for such a transition.
Therefore, Statement (I) is false.
Statement (II)
“$2 p_x$ and $2 p_y$ are degenerate orbitals.”
Orbitals within the same subshell (e.g., $2p$ subshell) are typically degenerate (same energy) in an isolated atom (especially a hydrogen-like atom).
Thus, $2 p_x$ and $2 p_y$ (and $2 p_z$) do indeed have the same energy.
Therefore, Statement (II) is true.
Conclusion
Statement (I): False
Statement (II): True
Hence, the correct choice is:
Option A: Statement I is false but Statement II is true.
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