JEE MAIN - Chemistry (2024 - 8th April Evening Shift - No. 12)

The equilibrium $$\mathrm{Cr}_2 \mathrm{O}_7^{2-} \rightleftharpoons 2 \mathrm{CrO}_4^{2-}$$ is shifted to the right in :
a weakly acidic medium
a basic medium
a neutral medium
an acidic medium

Explanation

The equilibrium $$\mathrm{Cr}_2 \mathrm{O}_7^{2-} \rightleftharpoons 2 \mathrm{CrO}_4^{2-}$$ can be influenced by changes in the pH of the medium, according to Le Chatelier's principle. This principle states that if a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to counteract the change.

In this case:

$$\mathrm{Cr}_2 \mathrm{O}_7^{2-}$$ is dichromate, which exists more prominently in acidic conditions. On the other hand, $$\mathrm{CrO}_4^{2-}$$ is chromate, which is favored in basic conditions. When the medium is basic, hydrogen ion concentration decreases, leading to the formation of more chromate ions ($$\mathrm{CrO}_4^{2-}$$).

Thus, in a basic medium, the reaction shifts to the right, resulting in the formation of $$2 \mathrm{CrO}_4^{2-}$$ from $$\mathrm{Cr}_2 \mathrm{O}_7^{2-}$$.

Therefore, the correct option is:

Option B: a basic medium

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