The number of element from the following that do not belong to lanthanoids is $$\mathrm{Eu}, \mathrm{Cm}, \mathrm{Er}, \mathrm{Tb}, \mathrm{Yb}$$ and $$\mathrm{Lu}$$

A conductivity cell with two electrodes (dark side) are half filled with infinitely dilute aqueous solution of a weak electrolyte. If volume is doubled by adding more water at constant temperature, the molar conductivity of the cell will -

Match List I with List II

	LIST I (Compound)		LIST II (Uses)
A.	Idoform	I.	Fire extinguisher
B.	Carbon tetrachloride	II.	Insecticide
C.	CFC	III.	Antiseptic
D.	DDT	IV.	Refrigerants

Choose the correct answer from the options given below:

At $$-20^{\circ} \mathrm{C}$$ and $$1 \mathrm{~atm}$$ pressure, a cylinder is filled with equal number of $$\mathrm{H}_2, \mathrm{I}_2$$ and $$\mathrm{HI}$$ molecules for the reaction $$\mathrm{H}_2(\mathrm{~g})+\mathrm{I}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{HI}(\mathrm{g})$$, the $$\mathrm{K}_{\mathrm{p}}$$ for the process is $$x \times 10^{-1}$$.

$$\mathrm{x}=$$ __________.

[Given : $$\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$]

The electron affinity value are negative for

A. $$\mathrm{Be} \rightarrow \mathrm{Be}^{-}$$

B. $$\mathrm{N} \rightarrow \mathrm{N}^{-}$$

C. $$\mathrm{O} \rightarrow \mathrm{O}^{2-}$$

D. $$\mathrm{Na} \rightarrow \mathrm{Na}^{-}$$

E. $$\mathrm{Al} \rightarrow \mathrm{Al}^{-}$$

Choose the most appropriate answer from the options given below :

Consider the following complexes

(A) $$\left[\mathrm{CoCl}\left(\mathrm{NH}_3\right)_5\right]^{2+}$$, (B) $$\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-}$$, (C) $$ \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{H}_2 \mathrm{O}\right)\right]^{3+} $$, (D) $$\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_4\right]^{2+}$$

The correct order of A, B, C and D in terms of wavenumber of light absorbed is :

Functional group present in sulphonic acids is :

Match List I with List II

	LIST I (Precipitating reagent and conditions)		LIST II (Cation)
A.	$$ \mathrm{NH}_4 \mathrm{Cl}+\mathrm{NH}_4 \mathrm{OH} $$	I.	$$\mathrm{Mn^{2+}}$$
B.	$$ \mathrm{NH}_4 \mathrm{OH}+\mathrm{Na}_2 \mathrm{CO}_3 $$	II.	$$\mathrm{Pb^{2+}}$$
C.	$$ \mathrm{NH}_4 \mathrm{OH}+\mathrm{NH}_4 \mathrm{Cl}+\mathrm{H}_2 \mathrm{~S} \text { gas } $$	III.	$$\mathrm{Al^{3+}}$$
D.	dilute $$\mathrm{HCl}$$	IV.	$$\mathrm{Sr^{2+}}$$

Choose the correct answer from the options given below:

Given below are two statements :

Statement I : Gallium is used in the manufacturing of thermometers.

Statement II : A thermometer containing gallium is useful for measuring the freezing point $$(256 \mathrm{~K})$$ of brine solution.

In the light of the above statements, choose the correct answer from the options given below :

The density of '$$x$$' $$\mathrm{M}$$ solution ('$$x$$' molar) of $$\mathrm{NaOH}$$ is $$1.12 \mathrm{~g} \mathrm{~mL}^{-1}$$, while in molality, the concentration of the solution is $$3 \mathrm{~m}$$ ( 3 molal). Then $$x$$ is

(Given : Molar mass of $$\mathrm{NaOH}$$ is $$40 \mathrm{~g} / \mathrm{mol}$$)

Match List I with List II

	LIST I (Compound/Species)		LIST II (Shape/Geometry)
A.	$$\mathrm{SF_4}$$	I.	Tetrahedral
B.	$$\mathrm{BrF_3}$$	II.	Pyramidal
C.	$$\mathrm{BrO_3^-}$$	III.	See saw
D.	$$\mathrm{NH_4^+}$$	IV.	Bent T-Shape

Choose the correct answer from the options given below:

Match List I with List II

	LIST I (Molecule/Species)		LIST II (Property/Shape)
A.	$$\mathrm{SO_2Cl_2}$$	I.	Paramagnetic
B.	$$\mathrm{NO}$$	II.	Diamagnetic
C.	$$\mathrm{NO_2^-}$$	III.	Tetrahedral
D.	$$\mathrm{I_3^-}$$	IV.	Linear

Choose the correct answer from the options given below:

Which of the following statements are correct?

A. Glycerol is purified by vacuum distillation because it decomposes at its normal boiling point.

B. Aniline can be purified by steam distillation as aniline is miscible in water.

C. Ethanol can be separated from ethanol water mixture by azeotropic distillation because it forms azeotrope.

D. An organic compound is pure, if mixed M.P. is remained same.

Choose the most appropriate answer from the options given below :

Which of the following material is not a semiconductor.

Which of the following is metamer of the given compound (X) ?

In Reimer - Tiemann reaction, phenol is converted into salicylaldehyde through an intermediate. The structure of intermediate is __________.

Which among the following aldehydes is most reactive towards nucleophilic addition reactions?

DNA molecule contains 4 bases whose structure are shown below. One of the structures is not correct, identify the incorrect base structure.

Match List I with List II

	LIST I (Hybridization)		LIST II (Orientation in Shape)
A.	sp$$^3$$	I.	Trigonal bipyramidal
B.	dsp$$^2$$	II.	Octahedral
C.	sp$$^3$$d	III.	Tetrahedral
D.	sp$$^3$$d$$^2$$	IV.	Square planar

Choose the correct answer from the options given below:

Given below are two statements :

Statement I : Piciric acid is 2,4,6 - trinitrotoluene.

Statement II : Phenol - 2,4 - disulphonic acid is treated with Conc. $$\mathrm{HNO}_3$$ to get picric acid.

In the light of the above statements, choose the most appropriate answer from the options given below :

The major product of the following reaction is P.

$$\mathrm{CH}_3 \mathrm{C}\equiv\mathrm{C}-\mathrm{CH}_3$$ $$\xrightarrow[\substack{\text { (ii) dil. } \mathrm{KMnO}_4 \\ 273 \mathrm{~K}}]{\text { (i) } \mathrm{Na} \text { /liq. } \mathrm{NH}_3}$$ 'P'

Number of oxygen atoms present in product '$$\mathrm{P}$$' is _______. (nearest integer)

Time required for $$99.9 \%$$ completion of a first order reaction is _________ times the time required for completion of $$90 \%$$ reaction.(nearest integer)

Consider the dissociation of the weak acid HX as given below

$$\mathrm{HX}(\mathrm{aq}) \rightleftharpoons \mathrm{H}^{+}(\mathrm{aq})+\mathrm{X}^{-}(\mathrm{aq}), \mathrm{Ka}=1.2 \times 10^{-5}$$

[$$\mathrm{K}_{\mathrm{a}}$$ : dissociation constant]

The osmotic pressure of $$0.03 \mathrm{M}$$ aqueous solution of $$\mathrm{HX}$$ at $$300 \mathrm{~K}$$ is _________ $$\times 10^{-2}$$ bar (nearest integer).

[Given : $$\mathrm{R}=0.083 \mathrm{~L} \mathrm{~bar} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$$]

An ideal gas, $$\overline{\mathrm{C}}_{\mathrm{v}}=\frac{5}{2} \mathrm{R}$$, is expanded adiabatically against a constant pressure of 1 atm untill it doubles in volume. If the initial temperature and pressure is $$298 \mathrm{~K}$$ and $$5 \mathrm{~atm}$$, respectively then the final temperature is _________ $$\mathrm{K}$$ (nearest integer).

[$$\overline{\mathrm{c}}_{\mathrm{v}}$$ is the molar heat capacity at constant volume]

The major products from the following reaction sequence are product A and product B.

The total sum of $$\pi$$ electrons in product A and product B are __________ (nearest integer)

The difference in the 'spin-only' magnetic moment values of $$\mathrm{KMnO}_4$$ and the manganese product formed during titration of $$\mathrm{KMnO}_4$$ against oxalic acid in acidic medium is ________ $$\mathrm{BM}$$. (nearest integer)

$$9.3 \mathrm{~g}$$ of pure aniline upon diazotisation followed by coupling with phenol gives an orange dye. The mass of orange dye produced (assume 100% yield/conversion) is ________ g. (nearest integer)

Number of molecules from the following which can exhibit hydrogen bonding is _________. (nearest integer)

Among $$\mathrm{CrO}, \mathrm{Cr}_2 \mathrm{O}_3$$ and $$\mathrm{CrO}_3$$, the sum of spin-only magnetic moment values of basic and amphoteric oxides is _________ $$10^{-2} \mathrm{BM}$$ (nearest integer).

(Given atomic number of $$\mathrm{Cr}$$ is 24 )

Frequency of the de-Broglie wave of electron in Bohr's first orbit of hydrogen atom is _________ $$\times 10^{13} \mathrm{~Hz}$$ (nearest integer).

[Given : $$\mathrm{R}_{\mathrm{H}}$$ (Rydberg constant) $$=2.18 \times 10^{-18} \mathrm{~J}, h$$ (Plank's constant) $$=6.6 \times 10^{-34} \mathrm{~J} . \mathrm{s}$$.]