JEE MAIN - Chemistry (2024 - 29th January Evening Shift - No. 8)

Which of the following statements are correct about $$\mathrm{Zn}, \mathrm{Cd}$$ and $$\mathrm{Hg}$$ ?

A. They exhibit high enthalpy of atomization as the d-subshell is full.

B. $$\mathrm{Zn}$$ and $$\mathrm{Cd}$$ do not show variable oxidation state while $$\mathrm{Hg}$$ shows $$+\mathrm{I}$$ and $$+\mathrm{II}$$.

C. Compounds of $$\mathrm{Zn}, \mathrm{Cd}$$ and $$\mathrm{Hg}$$ are paramagnetic in nature.

D. $$\mathrm{Zn}, \mathrm{Cd}$$ and $$\mathrm{Hg}$$ are called soft metals.

Choose the most appropriate from the options given below:

C, D only
B, C only
A, D only
B, D only

Explanation

(A) $$\mathrm{Zn}, \mathrm{Cd}, \mathrm{Hg}$$ exhibit lowest enthalpy of atomization in respective transition series.

(C) Compounds of $$\mathrm{Zn}, \mathrm{Cd}$$ and $$\mathrm{Hg}$$ are diamagnetic in nature.

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