JEE MAIN - Chemistry (2024 - 27th January Morning Shift - No. 27)
Among the following, total number of meta directing functional groups is (Integer based)
$$-\mathrm{OCH}_3,-\mathrm{NO}_2,-\mathrm{CN},-\mathrm{CH}_3-\mathrm{NHCOCH}_3, -\mathrm{COR},-\mathrm{OH},-\mathrm{COOH},-\mathrm{Cl}$$
Answer
4
Explanation
Here's how to identify the meta-directing functional groups and determine the total :
Meta-Directing Groups:- Meta-directing groups are electron-withdrawing. They destabilize the intermediate carbocation that forms during electrophilic aromatic substitution at the ortho and para positions more than at the meta position.
- Common meta-directing groups include:
- -NO₂ (nitro)
- -CN (cyano)
- -COR (carbonyl groups, like ketones and aldehydes)
- -COOH (carboxylic acid)
- -SO₃H (sulfonic acid)
Identifying Meta-Directing Groups in the List:
- -OCH₃: Ortho/para-directing (electron-donating)
- -NO₂: Meta-directing
- -CN: Meta-directing
- -CH₃: Ortho/para-directing (electron-donating)
- -NHCOCH₃: Ortho/para-directing (electron-donating)
- -COR: Meta-directing
- -OH: Ortho/para-directing (electron-donating)
- -COOH: Meta-directing
- -Cl: Ortho/para-directing (weakly deactivating)
Total Count:
There are four meta-directing groups in the list: -NO₂, -CN, -COR, -COOH
Answer:The total number of meta-directing functional groups is 4.
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