JEE MAIN - Chemistry (2023 - 8th April Morning Shift - No. 7)

Which halogen is known to cause the reaction given below :

$$2 \mathrm{Cu}^{2+}+4 \mathrm{X}^{-} \rightarrow \mathrm{Cu}_{2} \mathrm{X}_{2}(\mathrm{s})+\mathrm{X}_{2}$$

All halogens
Only Iodine
Only Bromine
Only Chlorine

Explanation

The given reaction describes the formation of a copper(II) halide and the corresponding diatomic halogen molecule. Not all halogens will cause this reaction to occur.

This reaction is known to occur with iodine (I) because the formation of $\mathrm{I}_{2}$ (a diatomic iodine molecule) is easier due to the relatively low bond energy of the $\mathrm{I}-\mathrm{I}$ bond.

On the other hand, the bond energies of $\mathrm{Cl}-\mathrm{Cl}$ and $\mathrm{Br}-\mathrm{Br}$ are higher, making it more difficult for these diatomic halogen molecules to form. Thus, these halogens would not typically cause this reaction to occur.

Therefore, the correct answer is:

Option B : Only Iodine.

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