JEE MAIN - Chemistry (2023 - 8th April Evening Shift - No. 5)

Henry Moseley studied characteristic X-ray spectra of elements. The graph which represents his observation correctly is

Given $$v=$$ frequency of $$\mathrm{X}$$-ray emitted

Z = atomic number

JEE Main 2023 (Online) 8th April Evening Shift Chemistry - Structure of Atom Question 39 English Option 1
JEE Main 2023 (Online) 8th April Evening Shift Chemistry - Structure of Atom Question 39 English Option 2
JEE Main 2023 (Online) 8th April Evening Shift Chemistry - Structure of Atom Question 39 English Option 3
JEE Main 2023 (Online) 8th April Evening Shift Chemistry - Structure of Atom Question 39 English Option 4

Explanation

Moseley's observation on characteristic X-ray spectra of elements relates frequency $(v)$ of X-rays emitted to the atomic number by the following relation:

$$ \sqrt{v}=a(Z-b) $$

The plot of $\sqrt{v}$ vs $\mathrm{Z}$ is linear with -ve intercept on Y-axis.

JEE Main 2023 (Online) 8th April Evening Shift Chemistry - Structure of Atom Question 39 English Explanation
Out of the four graphs given, graph (B) can be considered correct but it needs to be modified with respect to intercept on Y-axis.

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