JEE MAIN - Chemistry (2023 - 30th January Evening Shift - No. 7)
Explanation
Potassium permanganate ($\mathrm{KMnO}_4$) is a strong oxidizing agent that can oxidize iodide ions ($\mathrm{I}^{-}$) to different products depending on the pH of the solution.
In acidic solutions, $\mathrm{KMnO}_4$ oxidizes $\mathrm{I}^{-}$ to molecular iodine ($\mathrm{I}_2$) according to the following equation:
$$ 2\mathrm{MnO}_4^{-} + 16\mathrm{H}^{+} + 10\mathrm{I}^{-} \rightarrow 2\mathrm{Mn}^{2+} + 8\mathrm{H}_2\mathrm{O} + 5\mathrm{I}_2 $$In neutral or faintly alkaline solutions, the oxidation product is different because the $\mathrm{I}^{-}$ is oxidized to iodate ion ($\mathrm{IO}_3^{-}$). The reaction in a neutral or slightly alkaline solution is as follows:
$$ 2\mathrm{MnO}_4^{-} + 2\mathrm{H}_2\mathrm{O} + 10\mathrm{I}^{-} \rightarrow 2\mathrm{MnO}_2 + 4\mathrm{OH}^{-} + 5\mathrm{IO}_3^{-} $$So according to the reactions above, in acidic solutions, $\mathrm{I}^{-}$ is oxidized to $\mathrm{I}_2$ while in neutral or faintly alkaline solutions, $\mathrm{I}^{-}$ is oxidized to $\mathrm{IO}_3^{-}$. Therefore, the correct answer is:
Option C: $\mathrm{I}_2 ~\&~ \mathrm{IO}_3^{-}$
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