JEE MAIN - Chemistry (2023 - 13th April Evening Shift - No. 1)

What happens when methane undergoes combustion in systems A and B respectively?

JEE Main 2023 (Online) 13th April Evening Shift Chemistry - Thermodynamics Question 51 English

System A System B
Temperature falls Temperature rises
System A System B
Temperature rises Temperature remains same
System A System B
Temperature falls Temperature remains same
System A System B
Temperature remains same Temperature rises

Explanation

When methane undergoes combustion in systems A (adiabatic system) and B (diathermic container), the outcomes are as follows:

System A (adiabatic system): In an adiabatic system, no heat exchange occurs between the system and its surroundings. As methane undergoes combustion, which is an exothermic process, the heat generated by the reaction is retained within the system, causing the temperature to rise. Therefore, for System A, the temperature rises.

System B (diathermic container): In a diathermic container, heat exchange is allowed between the system and its surroundings. As methane undergoes combustion, the heat generated by the reaction is partially transferred to the surroundings. Depending on the heat capacity of the container and the extent of heat transfer, the temperature of the system may rise, remain the same, or even fall. However, in most cases, the temperature in System B would be expected to rise, but at a slower rate compared to System A.

Based on this information, the most appropriate option is:

System A: Temperature rises

System B: Temperature remains same

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