JEE MAIN - Chemistry (2021 - 26th February Evening Shift - No. 23)

The number of stereoisomers possible for [Co(ox)2(Br)(NH3)]2$$-$$ is ___________. [ox = oxalate]
Answer
3

Explanation

The coordination compound [Co(ox)2(Br)(NH3)]2$$-$$ of general formula [M(A - A)2BC] can show both geometrical and optical isomerism (stereoisomerism).

JEE Main 2021 (Online) 26th February Evening Shift Chemistry - Coordination Compounds Question 178 English Explanation 1

The cis-form produces non-superimposable mirror images, i.e. enantiomeric pairs (optically active)

JEE Main 2021 (Online) 26th February Evening Shift Chemistry - Coordination Compounds Question 178 English Explanation 2

The trans-form is optically inactive.

So, total number of stereoisomers possible = cis( $$ \pm $$ ) + trans = 3

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