JEE MAIN - Chemistry (2020 - 5th September Morning Slot - No. 5)
The structure of PCl5
in the solid state is :
square pyramidal
tetrahedral [PCl4]+ and octahedral [PCl6]–
square planar [PCl4]+ and octahedral [PCl6]–
trigonal bipyramidal
Explanation
In solid state PCl5
exist in Ionpair i.e. [PCl4]
+ and [PCl6]
–
[PCl4]+ is tetrahedral.
[PCl6]– is octahedral.
[PCl4]+ is tetrahedral.
[PCl6]– is octahedral.
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