JEE MAIN - Chemistry (2019 - 9th April Evening Slot - No. 6)

In the following reaction Rate of the reaction is the highest for :
Propanal as substrate and methanol in stoichiometric amount.
Acetone as substrate and methanol in stoichiometric amount
Propanal as substrate and methanol in excess
Acetone as substrate and methanol in excess

Explanation

Steric hindrance of aldehydes is less compares to the ketone that is why aldehydes are more reactive than ketones in nucleophilic addition reactions.

So among propanal and acetone, propanal is suitable as substance.

And to form acetal, excess amount of alcohol is required so here methanol in excess is required.

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