JEE MAIN - Chemistry (2019 - 8th April Morning Slot - No. 6)

The size of the iso-electronic species Cl,  Ar and Ca2+ is affected by :
electron-electron interaction in the outer orbitals
Principal quantum number of valence shell
nuclear charge
azimuthal quantum number of valence shell

Explanation

Cl- Ar Ca+2
Protons 17 18 20
Electrons 18 18 18

Nuclear charge means number of protons present in the nucleus. Here maximum number of protons present in the Ca+2 ion, so the attraction towards those 18 electrons wll be most by the nucleus of the Ca+2 ion. That is why size of the Ca+2 ion wll be least because of highest nuclear charge.

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