JEE MAIN - Chemistry (2019 - 12th April Morning Slot - No. 10)
In the following reaction; xA $$ \to $$ yB
$${\log _{10}}\left[ { - {{d\left[ A \right]} \over {dt}}} \right] = {\log _{10}}\left[ {{{d\left[ B \right]} \over {dt}}} \right] + 0.3010$$
'A' and 'B' respectively can be :
$${\log _{10}}\left[ { - {{d\left[ A \right]} \over {dt}}} \right] = {\log _{10}}\left[ {{{d\left[ B \right]} \over {dt}}} \right] + 0.3010$$
'A' and 'B' respectively can be :
n-Butane and Iso-butane
C2H4 and C4H8
C2H4 and C6H6
N2O4 and NO2
Explanation
xA $$ \to $$ yB
$${1 \over x}\left\{ { - {{d\left[ A \right]} \over {dt}}} \right\} = {1 \over y}\left\{ {{{d\left[ B \right]} \over {dt}}} \right\}$$
$$ \Rightarrow $$ $$ - {{d\left[ A \right]} \over {dt}} = {x \over y}\left\{ {{{d\left[ B \right]} \over {dt}}} \right\}$$
Taking log both sides, we get
$$ \Rightarrow $$ $${\log _{10}}\left[ { - {{d\left[ A \right]} \over {dt}}} \right] = {\log _{10}}\left[ {{{d\left[ B \right]} \over {dt}}} \right] + {\log _{10}}\left( {{x \over y}} \right)$$
Given that,
$${\log _{10}}\left[ { - {{d\left[ A \right]} \over {dt}}} \right] = {\log _{10}}\left[ {{{d\left[ B \right]} \over {dt}}} \right] + 0.3010$$
So, by comparing both of them we get
$${\log _{10}}\left( {{x \over y}} \right)$$ = 0.3010 = $${\log _{10}}\left( 2 \right)$$
$$ \therefore $$ $${{x \over y}}$$ = 2
$$ \Rightarrow $$ x = 2y
If x = 2 then y = 1
The reaction is of type 2A $$ \to $$ B
So possible reaction is
2C2H4 $$ \to $$ C4H8
$${1 \over x}\left\{ { - {{d\left[ A \right]} \over {dt}}} \right\} = {1 \over y}\left\{ {{{d\left[ B \right]} \over {dt}}} \right\}$$
$$ \Rightarrow $$ $$ - {{d\left[ A \right]} \over {dt}} = {x \over y}\left\{ {{{d\left[ B \right]} \over {dt}}} \right\}$$
Taking log both sides, we get
$$ \Rightarrow $$ $${\log _{10}}\left[ { - {{d\left[ A \right]} \over {dt}}} \right] = {\log _{10}}\left[ {{{d\left[ B \right]} \over {dt}}} \right] + {\log _{10}}\left( {{x \over y}} \right)$$
Given that,
$${\log _{10}}\left[ { - {{d\left[ A \right]} \over {dt}}} \right] = {\log _{10}}\left[ {{{d\left[ B \right]} \over {dt}}} \right] + 0.3010$$
So, by comparing both of them we get
$${\log _{10}}\left( {{x \over y}} \right)$$ = 0.3010 = $${\log _{10}}\left( 2 \right)$$
$$ \therefore $$ $${{x \over y}}$$ = 2
$$ \Rightarrow $$ x = 2y
If x = 2 then y = 1
The reaction is of type 2A $$ \to $$ B
So possible reaction is
2C2H4 $$ \to $$ C4H8
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