JEE MAIN - Chemistry (2018 (Offline) - No. 26)

The ratio of mass percent of C and H of an organic compound (CXHYOZ) is 6 : 1. If one molecule of the above compound (CXHYOZ) contains half as much oxygen as required to burn one molecule of compound CXHY completely to CO2 and H2O. The empirical formula of compound CXHYOZ is
C2H4O3
C3H6O3
C2H4O
C3H4O2

Explanation

JEE Main 2018 (Offline) Chemistry - Some Basic Concepts of Chemistry Question 191 English Explanation

$$\therefore\,\,\,$$ The ratio of no of atoms of C and H in one molecule of Cx Hy Oz = 1 : 2

$$\therefore\,\,\,$$ y = 2x

In one molecule of Cx Hy Oz compound contain z atoms of oxygen.

According to the question, no of atoms of oxygen required to burn CxHy completely should be twice of z atoms of oxygen.

CxHy + (x + $${y \over 4}$$) O2 $$ \to $$ HCO2 + $${y \over 2}$$ H2O

No. of O2 molecules required = (x + $${y \over 4}$$)

$$\therefore\,\,\,$$ No. of O atoms required = 2 (x + $${y \over 4}$$)

According to question,

$$2\left( {x + {y \over 4}} \right) = 2z$$

$$ \Rightarrow \,\,\,2\left( {x + {{2x} \over 4}} \right) = 2z\,\,\,$$ [ Putting y = 2x ]

$$ \Rightarrow \,\,\,\,{{3x} \over 2} = z$$

$$\therefore\,\,\,$$ x : y : z

= x : 2x : $${{3x} \over 2}$$

= 2 : 4 : 3

$$\therefore\,\,\,$$ Empirical formula = C2H4O3

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