JEE MAIN - Chemistry (2017 - 8th April Morning Slot - No. 14)
If the shortest wavelength in Lyman series of hydrogen atom is A, then the longest wavelength in Paschen series of He+ is :
$${{5A} \over 9}$$
$${{9A} \over 5}$$
$${{36A} \over 5}$$
$${{36A} \over 7}$$
Explanation
Note :
(1) In Lyman Series, transition happens in n = 1 state
from n = 2, 3, . . . . . $$ \propto $$
(2) In Balmer Series, transition happens in n = 2 state
from n = 3, 4, . . . . . $$ \propto $$
(3) In Paschen Series, transition happens in n = 3 state
from n = 4, 5, . . . . . $$ \propto $$
(4) In Bracktt Series, transition happens in n = 4 state
from n = 5, 6 . . . . . . $$ \propto $$
(5) In Pfund Series, transition happens in n = 5 state
from n = 6, 7, . . . . $$ \propto $$
We know,
$${1 \over \lambda }$$ = Rz2 ($${1 \over {n_1^2}}$$ $$-$$ $${1 \over {n_2^2}}$$)
The shortest wavelength of hydrogen atom in Lyman series is from n1 = 1 to n2 = $$ \propto $$
$$\therefore\,\,\,$$ $${1 \over A}$$ = 12 R ($${1 \over {{1^2}}}$$ $$-$$ $${1 \over {{ \propto ^2}}}$$) [for hydrogen, z = 1]
$$ \Rightarrow $$ $$\,\,\,$$ $${1 \over A}$$ = R
The longest wavelength in pascal series of He+ is from n1 = 3 to n2 = 4
For He+, z = 2.
$${1 \over \lambda }$$ = RZ2 ($${1 \over {n_1^2}}$$ $$-$$ $${1 \over {n_2^2}}$$)
$$ \Rightarrow $$$$\,\,\,$$ $${1 \over \lambda }$$ = $${1 \over A}$$ (2)2 ($${1 \over {{3^2}}}$$ $$-$$ $${1 \over {{4^2}}}$$)
$$ \Rightarrow $$$$\,\,\,$$ $${1 \over \lambda }$$ = $${4 \over A}$$ $$\left( {{7 \over {16 \times 9}}} \right)$$ = $${7 \over {36A}}$$
$$ \Rightarrow $$$$\,\,\,$$ $$\lambda $$ = $${{36A} \over 7}$$
(1) In Lyman Series, transition happens in n = 1 state
from n = 2, 3, . . . . . $$ \propto $$
(2) In Balmer Series, transition happens in n = 2 state
from n = 3, 4, . . . . . $$ \propto $$
(3) In Paschen Series, transition happens in n = 3 state
from n = 4, 5, . . . . . $$ \propto $$
(4) In Bracktt Series, transition happens in n = 4 state
from n = 5, 6 . . . . . . $$ \propto $$
(5) In Pfund Series, transition happens in n = 5 state
from n = 6, 7, . . . . $$ \propto $$
We know,
$${1 \over \lambda }$$ = Rz2 ($${1 \over {n_1^2}}$$ $$-$$ $${1 \over {n_2^2}}$$)
The shortest wavelength of hydrogen atom in Lyman series is from n1 = 1 to n2 = $$ \propto $$
$$\therefore\,\,\,$$ $${1 \over A}$$ = 12 R ($${1 \over {{1^2}}}$$ $$-$$ $${1 \over {{ \propto ^2}}}$$) [for hydrogen, z = 1]
$$ \Rightarrow $$ $$\,\,\,$$ $${1 \over A}$$ = R
The longest wavelength in pascal series of He+ is from n1 = 3 to n2 = 4
For He+, z = 2.
$${1 \over \lambda }$$ = RZ2 ($${1 \over {n_1^2}}$$ $$-$$ $${1 \over {n_2^2}}$$)
$$ \Rightarrow $$$$\,\,\,$$ $${1 \over \lambda }$$ = $${1 \over A}$$ (2)2 ($${1 \over {{3^2}}}$$ $$-$$ $${1 \over {{4^2}}}$$)
$$ \Rightarrow $$$$\,\,\,$$ $${1 \over \lambda }$$ = $${4 \over A}$$ $$\left( {{7 \over {16 \times 9}}} \right)$$ = $${7 \over {36A}}$$
$$ \Rightarrow $$$$\,\,\,$$ $$\lambda $$ = $${{36A} \over 7}$$
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