The major product obtained in the following reaction is :
Answer
(D)
2
Which of the following compounds will behave as a reducing sugar in an aqueous KOH solution?
Answer
(D)
3
The correct sequence of reagents for the following conversion will be :
Answer
(C)
[Ag(NH3)2]+OH-, H+/ CH3OH, CH3MgBr
4
Sodium salt of an organic acid ‘X’ produces effervescence with conc. H2SO4. ‘X’ reacts with the acidified
aqueous CaCl2 solution to give a white precipitate which decolourises acidic solution of KMnO4. ‘X’ is :
Answer
(B)
Na2C2O4
5
The major product obtained in the following reaction is :
Answer
(A)
C6H5CH = CHC6H5
6
Which of the following, upon treatment with tert-BuONa followed by addition of bromine water, fails to
decolorize the colour of bromine?
Answer
(A)
7
3-Methyl-pent-2-ene on reaction with HBr in presence of peroxide forms an addition product. The number
of possible stereoisomers for the product is :
Answer
(C)
Four
8
The increasing order of the reactivity of the following halides for the SN1 reaction is :
Answer
(A)
(II) < (I) < (III)
9
Which of the following compounds will form significant amount of meta product during mono-nitration
reaction?
Answer
(B)
10
Which of the following molecules is least resonance stabilized?
Answer
(C)
11
On treatment of 100 mL of 0.1 M solution of CoCl3. 6H2O with excess AgNO3; 1.2 $$\times$$ 1022 ions are precipitated. The complex is :
Answer
(C)
[Co(H2O)5Cl]Cl2.H2O
12
In the following reactions, ZnO is respectively acting as a/an :
(a) ZnO + Na2O $$\to$$ Na2ZnO2
(b) ZnO + CO2 $$\to$$ ZnCO3
Answer
(C)
acid and base
13
The most abundant elements by mass in the body of a healthy human adult are: Oxygen (61.4%); Carbon
(22.9%), Hydrogen (10.0%); and Nitrogen (2.6%). The weight which a 75 kg person would gain if all
1H atoms are replaced by 2H atoms is:
Answer
(B)
7.5 kg
14
Two reactions R1 and R2 have identical pre-exponential factors. Activation energy of R1 exceeds that of R2 by 10 kJ mol–1. If k1 and k2 are rate constants for reactions R1 and R2 respectively at 300 K, then ln(k2/k1) is equal to :
(R = 8.314 J mol–1 K–1)
Answer
(C)
4
15
Which of the following reactions is an example of a redox reaction?
Answer
(C)
$$Xe{F_4}$$ + O2F2 $$\to$$ $$Xe{F_6}$$ + O2
16
pKa of a weak acid (HA) and pKb of a weak base (BOH) are 3.2 and 3.4, respectively. The pH of their salt (AB) solution is :
Answer
(A)
6.9
17
Two reactions R1 and R2 have identical pre-exponential factors. Activation energy of R1 exceeds that of R2 by 10 kJ mol–1. If k1 and k2 are rate constants for reactions R1 and R2 respectively at 300 K, then ln(k2/k1) is equal to :
(R = 8.314 J mol–1 K–1)
Answer
(C)
4
18
Which of the following reactions is an example of a redox reaction?
Answer
(C)
$$Xe{F_4}$$ + O2F2 $$\to$$ $$Xe{F_6}$$ + O2
19
pKa of a weak acid (HA) and pKb of a weak base (BOH) are 3.2 and 3.4, respectively. The pH of their salt (AB) solution is :
Answer
(A)
6.9
20
Given
$$E_{C{l_2}/C{l^ - }}^o$$ = 1.36 V, $$E_{C{r^{3 + }}/Cr}^o$$ = - 0.74 V
$$E_{C{r_2}{O_7}^{2 - }/C{r^{3 + }}}^o$$ = 1.33 V, $$E_{Mn{O_4}^ - /Mn ^{2+}}^o$$ = 1.51 V
Among the following, the strongest reducing agent is :
Based on the above thermochemical equations, the value of $${\Delta _r}{H^o}$$ at 298 K for the reaction
$${C_{(graphite)}}$$ + $$2{{\rm H}_2}(g) \to$$ $$C{H_4}(g)$$ will be :
Answer
(B)
– 74.8 kJ mol–1
22
The freezing point of benzene decreases by 0.450C when 0.2 g of acetic acid is added to 20g of benzene. If
acetic acid associates to form a dimer in benzene, percentage association of acetic acid in benzene will be:
(Kf for benzene = 5.12 K kg mol–1)