JEE MAIN - Chemistry (2016 - 10th April Morning Slot - No. 9)
The transition metal ions responsible for color in ruby and emerald are,
respectively :
Cr3+ and Co3+
Co3+ and Cr3+
Co3+ and Co3+
Cr3+ and Cr3+
Explanation
On addition of impurities to the colourless gemstones, brilliant colours are produced. On addition of chromium to colourless corundum (Al2O3), a red ruby is formed. Red colour ruby is obtained when Cr3+ ions replace Al3+ ions in the octahedral sites of corundum. A green emerald emerges when chromium is added to colourless beryl (Be3Al2(SiO3)6). Green colour emerald is obtained when Cr3+ ions replace Al3+ in the octahedral site of beryl.
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