JEE MAIN - Chemistry (2013 (Offline) - No. 24)
Experimentally it was found that a metal oxide has formula M0.98O. Metal M, present as M2+ and M3+ in its oxide. Fraction of the metal which exists as M3+ would be
7.01%
4.08%
6.05%
5.08%
Explanation
Given metal oxide = M0.98O
We know oxidation number of O = (-2)
Now assume oxidaton no of M = $$x$$
$$\therefore$$ 0.98$$x$$ + 1$$ \times $$ (-2) = 0
$$ \Rightarrow x =$$ $${{200} \over {98}}$$
This represent the charge in one atom of M. As you can see the charge of M is in the range $$2 < {{200} \over {98}} < 3$$.
So we can say in M mixture of M+2 and M+3 present.
Assume total no of atoms present in M is 100.
Let M+3 present in M = y atoms
So M+2 present in M = (100 - y) atoms
In 1 atom of M+3 charge present = +3
So in y atoms of M+3 charge present = +3y
Similarly in 1 atom of M+2 charge present = +2
So in (100 - y) atoms of M+2 charge present = +2(100 - y)
$$\therefore$$ Total charge = 200 - 2y + 3y = 200 + y
In 100 atoms of M total charge = 200 + y
So in 1 atoms of M total charge = $${{200 + y} \over {100}}$$
Earlier we found that charge in one atom of M is = $${{200} \over {98}}$$
So we can write,
$${{200 + y} \over {100}}$$ = $${{200} \over {98}}$$
$$ \Rightarrow y = 4.08$$
So Option (B) is correct.
We know oxidation number of O = (-2)
Now assume oxidaton no of M = $$x$$
$$\therefore$$ 0.98$$x$$ + 1$$ \times $$ (-2) = 0
$$ \Rightarrow x =$$ $${{200} \over {98}}$$
This represent the charge in one atom of M. As you can see the charge of M is in the range $$2 < {{200} \over {98}} < 3$$.
So we can say in M mixture of M+2 and M+3 present.
Assume total no of atoms present in M is 100.
Let M+3 present in M = y atoms
So M+2 present in M = (100 - y) atoms
In 1 atom of M+3 charge present = +3
So in y atoms of M+3 charge present = +3y
Similarly in 1 atom of M+2 charge present = +2
So in (100 - y) atoms of M+2 charge present = +2(100 - y)
$$\therefore$$ Total charge = 200 - 2y + 3y = 200 + y
In 100 atoms of M total charge = 200 + y
So in 1 atoms of M total charge = $${{200 + y} \over {100}}$$
Earlier we found that charge in one atom of M is = $${{200} \over {98}}$$
So we can write,
$${{200 + y} \over {100}}$$ = $${{200} \over {98}}$$
$$ \Rightarrow y = 4.08$$
So Option (B) is correct.
Comments (0)
