JEE MAIN - Chemistry (2011 - No. 17)

The magnetic moment (spin only) of [NiCl4]2− is
5.46 BM
2.82 BM
1.41 BM
1.82 BM

Explanation

$${\left[ {NiC{l_4}} \right]^{2 - }}\,\left( {{d^8}} \right)$$

AIEEE 2011 Chemistry - Coordination Compounds Question 264 English Explanation

i.e. the number of unpaired electrons in $${\left[ {NiCl{}_4} \right]^{2 - }}\,\,$$ is $$2.$$

$$n = \sqrt {n\left( {n + 2} \right)} = \sqrt {2\left( 4 \right)} $$

$$ = 2\sqrt 2 = 2 \times 1.41$$

$$ = 2.82\,BM$$

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