JEE MAIN - Chemistry (2010 - No. 14)

From amongst the following alcohols the one that would react fastest with conc. HCl and anhydrous ZnCl2, is
2–Butanol
2–Methylpropan–2–ol
2–Methylpropanol
1–Butanol

Explanation

Tertiary alcohols react fastest with conc. $$HCl$$ and anhydrous $$ZnC{l_2}$$ (lucas reagent) as its mechanism proceeds through the formation of stable tertiary carbocation.

Mechanism

AIEEE 2010 Chemistry - Alcohols, Phenols and Ethers Question 158 English Explanation

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