JEE MAIN - Chemistry (2006 - No. 43)

Density of a 2.05M solution of acetic acid in water is 1.02 g/mL The molality of the solution is
2.28 mol kg-1
0.44 mol kg-1
1.14 mol kg-1
3.28 mol kg-1

Explanation

2.05M solution of acetic acid in water means in 1 litre solution 2.05 moles of CH3COOH present.

Density of solution = 1.02 g/ml (Given)

Assume the volume of solution = 1 litre = 1000 ml

$$\therefore$$ Mass of solution = 1000 $$ \times $$ 1.02 = 1020 gm

Molar mass of CH3COOH = 60

So Mass of CH3COOH (msolute) = 2.05 $$ \times $$ 60 = 123

$$\therefore$$ Mass of solvent (msolvent) = 1020 - 123 = 897 gm = 0.897 kg

Formula of molality (m) = $${{no\,of\,moles\,of\,solute} \over {weight\,of\,solvent\,in\,kg}}$$

$$\therefore$$ m = $${{2.05} \over {0.897}}$$ = 2.28

Using Formula :

Molality (m) = $${{1000 \times M} \over {1000 \times d - M \times {M_{solute}}}}$$

Here M = molarity, Msolute = molecular mass of solute, d = density of solution

$$\therefore$$ m = $${{1000 \times 2.05} \over {1000 \times 1.02 - 2.05 \times 60}}$$ = 2.28

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