JEE MAIN - Chemistry (2003 - No. 20)
Complete hydrolysis of cellulose gives
D-ribose
D-glucose
L-glucose
D-fructose
Explanation
Cellulose is a linear polymer of $$\beta $$ $$ - D - $$ glucose in which $${C_1}$$ of one glucose unit is connected to $${C_4}$$ of the other through $$\beta - D$$ glucosidic linkage. It does not undergo hydrolysis easily. However on heating with dilute $${H_2}S{O_4}$$ under pressure. It does undergo hydrolysis to give only $$D-$$ glucose.
$$$\left( {{C_6}{H_{10}}{O_5}} \right)n + n{H_2}O\buildrel {\,H + } \over \longrightarrow \mathop {n{C_6}{H_{12}}{O_6}}\limits_{D - Glu\cos e} $$$
$$$\left( {{C_6}{H_{10}}{O_5}} \right)n + n{H_2}O\buildrel {\,H + } \over \longrightarrow \mathop {n{C_6}{H_{12}}{O_6}}\limits_{D - Glu\cos e} $$$
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