JEE MAIN - Chemistry (2002 - No. 61)

For a cell given below

AIEEE 2002 Chemistry - Electrochemistry Question 46 English
$$ \begin{aligned} \mathrm{Ag}^{+}+\mathrm{e}^{-} & \longrightarrow \mathrm{Ag}; E^{\circ}=x \\\\ \mathrm{Cu}^{2+}+2 e^{-} & \longrightarrow \mathrm{Cu}{;} E^{\circ}=y \end{aligned} $$

$$ E^{\circ} \text { cell is } $$ :
$x+2 y$
$2 x+y$
$y-x$
$y-2 x$

Explanation

The cell notation indicates that the left side (Ag|Ag+) is the anode (oxidation occurs), and the right side (Cu²⁺|Cu) is the cathode (reduction occurs). In a galvanic (voltaic) cell, electrons flow from anode to cathode.

The standard cell potential (E° cell) is the difference in potential between the cathode and anode. It's calculated as :

cell = E°cathode - E°anode

At LHS (oxidation) :

$$ 2 \times\left(\mathrm{Ag} \longrightarrow \mathrm{Ag}^{+}+\mathrm{e}^{-}\right); \quad E_{\text {oxi }}^{\circ}=-x $$

At RHS (reduction) :

$$ \mathrm{Cu}^{2+}+2 e^{-} \longrightarrow \mathrm{Cu}; \quad \mathrm{E}_{\text {red }}^{\circ}=+y $$

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$$ 2 \mathrm{Ag}+\mathrm{Cu}^{2+} \longrightarrow \mathrm{Cu}+2 \mathrm{Ag}^{+}, E_{\text {cell }}^{\circ}=(y-x) $$
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$$ \therefore $$ E°cell = y - x

Therefore, the correct answer is :

Option C : y - x.

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