JEE MAIN - Chemistry (2002 - No. 58)
Hybridisation of underline atom changes in
$$\underline {Al} {H_3}$$ changes to $$AlH_4^-$$
$${H_2}\underline O $$ changes to $$H_3O^+$$
$$\underline N {H_3}$$ changes to $$NH_4^+$$
in all cases
Explanation
(a) $$\,\,\,$$ AlH3 + H$$-$$ $$ \to $$ AlH$$_4^ - $$
Steric number of AlH3 is = $${1 \over 2}$$ [3 + 3] = 3
$$\therefore\,\,\,$$ AlH3 is sp2 hybridized.
Steric number of AlH$$_4^ - $$ = $${1 \over 2}$$ [3 + 4 +1] = 4
$$\therefore\,\,\,$$ AlH$$_4^ - $$ is sp3 hybridized.
(b) $$\,\,\,$$ H2O + H+ $$ \to $$ H3O+
Steric no of H2O = $${1 \over 2}$$ (6+ 2) = 4
$$\therefore\,\,\,\,$$ H2O s sp3 hybridized.
Steric no of H3O+ = $${1 \over 2}$$ [ 8 + 3 $$-$$1] = 4
$$\therefore\,\,\,$$ H3O+ s also sp3 hybridized.
(c) $$\,\,\,$$ NH3 + H+ $$ \to $$ NH4+
Steric no of NH3 = $${1 \over 2}$$ [5 + 3] = 4
$$\therefore\,\,\,$$ hybridization of NH3 is sp3
Steric number of NH4+ = $${1 \over 2}$$ [5 + 4 $$-$$ ] = 4
$$\therefore\,\,\,$$ Hybridization of NH4+ is sp3
Steric number of AlH3 is = $${1 \over 2}$$ [3 + 3] = 3
$$\therefore\,\,\,$$ AlH3 is sp2 hybridized.
Steric number of AlH$$_4^ - $$ = $${1 \over 2}$$ [3 + 4 +1] = 4
$$\therefore\,\,\,$$ AlH$$_4^ - $$ is sp3 hybridized.
(b) $$\,\,\,$$ H2O + H+ $$ \to $$ H3O+
Steric no of H2O = $${1 \over 2}$$ (6+ 2) = 4
$$\therefore\,\,\,\,$$ H2O s sp3 hybridized.
Steric no of H3O+ = $${1 \over 2}$$ [ 8 + 3 $$-$$1] = 4
$$\therefore\,\,\,$$ H3O+ s also sp3 hybridized.
(c) $$\,\,\,$$ NH3 + H+ $$ \to $$ NH4+
Steric no of NH3 = $${1 \over 2}$$ [5 + 3] = 4
$$\therefore\,\,\,$$ hybridization of NH3 is sp3
Steric number of NH4+ = $${1 \over 2}$$ [5 + 4 $$-$$ ] = 4
$$\therefore\,\,\,$$ Hybridization of NH4+ is sp3
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