JEE MAIN - Chemistry (2002 - No. 48)

A square planar complex is formed by hybridisation of which atomic orbitals ?
s, px, py, dxy
s, px, py, dx2 - y2
s, px, py, dz2
s, px, py, dyz

Explanation

Hybridization of square planar complex is dsp2 .

AIEEE 2002 Chemistry - Chemical Bonding & Molecular Structure Question 200 English Explanation 1

In square planar complex all 4 surrounding atoms and central atom are in the same plane and let this plane is x $$-$$ y plane. As it is dsp2 hybridized, so it has 1 d orbital, 1 s orbital and 2 p orbital.

s orbital is non-directional, so we just write it as s.

AIEEE 2002 Chemistry - Chemical Bonding & Molecular Structure Question 200 English Explanation 2

In px the two lobes are along x-axis and in py two lobes are along y-axis

One d orbital is dx2 $$-$$ y2, it means out of four lobes of d orbital two along x-axis and two along y-axis.

AIEEE 2002 Chemistry - Chemical Bonding & Molecular Structure Question 200 English Explanation 3

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