JAMB - Chemistry (2025 - No. 57)

CH\(_3\) - CH\(_2\) - COOCH\(_2\) - CH\(_3\)

From the condensed structure above, the reactants are

ethanol and ethanoic acid
propanol and propanoic acid
propanol and ethanoic acid
propanoic acid and ethanol

Explanation

To identify the specific acid and alcohol reactants, we can reverse this process by adding water back to the ester molecule: The part with the carbonyl group (\(\text{COO}\)) comes from the carboxylic acid. The \(\text{CH}_{3}\text{CH}_{2}\text{COO}\) part corresponds to propanoic acid (\(\text{CH}_{3}\text{CH}_{2}\text{COOH}\)).The alkyl group attached to the oxygen atom (\(\text{O}\)) comes from the alcohol. The \(\text{CH}_{2}\text{CH}_{3}\) group corresponds to ethanol (\(\text{CH}_{3}\text{CH}_{2}\text{OH}\)). Thus, the reaction that forms ethyl propanoate is between propanoic acid and ethanol.

A. ethanol and ethanoic acid: These reactants would form ethyl ethanoate (\(\text{CH}_{3}\text{COOCH}_{2}\text{CH}_{3}\)), not ethyl propanoate.

B. propanol and propanoic acid: These reactants would form propyl propanoate (\(\text{CH}_{3}\text{CH}_{2}\text{COOCH}_{2}\text{CH}_{2}\text{CH}_{3}\)), which has a three-carbon chain on both sides of the ester link, unlike the given structure.

C. propanol and ethanoic acid: These reactants would form propyl ethanoate (\(\text{CH}_{3}\text{COOCH}_{2}\text{CH}_{2}\text{CH}_{3}\)), which also does not match the given structure.

The correct option is D. propanoic acid and ethanol.

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