JAMB - Chemistry (2025 - No. 57)
CH\(_3\) - CH\(_2\) - COOCH\(_2\) - CH\(_3\)
From the condensed structure above, the reactants are
Explanation
To identify the specific acid and alcohol reactants, we can reverse this process by adding water back to the ester molecule: The part with the carbonyl group (\(\text{COO}\)) comes from the carboxylic acid. The \(\text{CH}_{3}\text{CH}_{2}\text{COO}\) part corresponds to propanoic acid (\(\text{CH}_{3}\text{CH}_{2}\text{COOH}\)).The alkyl group attached to the oxygen atom (\(\text{O}\)) comes from the alcohol. The \(\text{CH}_{2}\text{CH}_{3}\) group corresponds to ethanol (\(\text{CH}_{3}\text{CH}_{2}\text{OH}\)). Thus, the reaction that forms ethyl propanoate is between propanoic acid and ethanol.
A. ethanol and ethanoic acid: These reactants would form ethyl ethanoate (\(\text{CH}_{3}\text{COOCH}_{2}\text{CH}_{3}\)), not ethyl propanoate.
B. propanol and propanoic acid: These reactants would form propyl propanoate (\(\text{CH}_{3}\text{CH}_{2}\text{COOCH}_{2}\text{CH}_{2}\text{CH}_{3}\)), which has a three-carbon chain on both sides of the ester link, unlike the given structure.
C. propanol and ethanoic acid: These reactants would form propyl ethanoate (\(\text{CH}_{3}\text{COOCH}_{2}\text{CH}_{2}\text{CH}_{3}\)), which also does not match the given structure.
The correct option is D. propanoic acid and ethanol.
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