JAMB - Chemistry (2024 - No. 32)

What method is suitable for the separation of gases present in air?
Catalytic cracking of liquid air
Fractional distillation of liquid air
Thermal decomposition of air
Catalytic decomposition of air

Explanation

Fractional distillation is the most common method for separating the gases in air. This method is used because the gases in air have a difference in boiling points of less than 25 K, making them suitable for fractional distillation.

Here's how fractional distillation works:

1. Liquefy the gases: Air is converted into liquid air by increasing the pressure and decreasing the temperature. 

2. Separate carbon dioxide and water vapour: As the temperature drops below 0°C, carbon dioxide separates as dry ice and water vapor separates as ice. 

3. Pass the liquid air through a column: The liquid air is then passed through a fractional distillation column, where the gases are separated based on their boiling points.

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