JAMB - Chemistry (1989 - No. 14)

Using 50 cm\(^3\) of 1 M potassium hydroxide and 100 cm\(^3\) of 1 M tetraoxosulphate (VI) acid, calculate the respective volumes in cm\(^3\) of base and acid that would be required to produce the maximum amount of potassium tetraoxosulphate (IV) [K = 39, S = 32, O = 16, H = 1]
50, 50
25, 50
50, 25
25, 25

Explanation

First, let's write a balanced equation for the chemical reaction:

 2KOH + H\(_2\)SO\(_4\) → K\(_2\)SO\(_4\) + 2H\(_2\)O

Reacting ratio: 2moles  : 1 mole 1 mole

Reacting Volume:   50cm\(^3\)  :  100cm\(^3\)

Actual volume that reacted:  50cm\(^3\)  : 25cm\(^3\)

Residual : 0cm\(^3\) : 75cm\(^3\) 

 

Volume of base (KOH) = 50 cm\(^3\)

Volume of acid (H\(_2\)SO\(_4\)) = 25 cm\(^3\)

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