JAMB - Chemistry (1979 - No. 39)
Phosphorus burns in oxygen according to the equation P\(_4\) + 5 0\(_2\) → P\(_4\)O\(_{10}\). How many litres of oxygen will be required at S.T.P for complete oxidation of 12.4g of phosphorus? [P = 31,O = 16 and molar volume of a gas at S.T.P = 22.4 litres]
5. 20
11. 20
2. 24
20. 20
6. 20
Explanation
P\(_4\) + 50\(_2\) → P\(_4\)O\(_{10}\)
for the complete combustion of 124 grammes of phosphorus we need
5 x 22.4 litres of 0\(_2\)
for 12.4 gms of P\(_4\) we need
\(\frac{5 \times 22.4}{124} \times \frac{12.4}{1}\)
\(\frac{22.4}{2}\) = 11.2 litres
Alternatively,
P\(_4\) + 5 0\(_2\) → P\(_4\)O\(_{10}\)
1 mole : 5 moles
Mass of P\(_4\) = 12.4
Molar mass of P\(_4\) = (31 x 4)=124g/mol
n = \(\frac{mass}{Molar mass}\)
= \(\frac{12.4}{124}\)
= 0.1 mole
Then 0.1 mole P\(_4\) will react with 0.5 mole 0\(_2\)
But n = \(\frac{Volume}{Molar Volume}\)
0.5 = \(\frac{Volume}{22.4}\)
V = 0.5 X 22.4
V = 11.20 Litres
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