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JAMB - Chemistry (2007 - No. 35)

Which of the following compounds is the best possible anti-knock agent for petrol?
(CH3)2CH - CH(CH3)CH2CH3
CH3CH2(CH3)CHCH2CH2CH3
CH3CH2(CH3)CHCH2CH2CH3
(CH3)3C - CH2CH2CH3

설명

An "anti-knock agent" for petrol (or gasoline) is a chemical additive that is added to fuel to prevent engine knocking, which is a knocking sound produced by premature ignition in the combustion chamber, and essentially increases the fuel's octane rating by delaying ignition.

Option A - 2,3- dimethylpentane

Option B - 3-methylhexane

Option C - 3-methylhexane

Option D - 2,2-dimethylpentane

Both 2,3-dimethylpentane and 2,2-dimethylpentane are branched-chain structures. However, 2,2-dimethylpentane has a more compact, highly branched structure, which is generally associated with higher octane ratings and better anti-knock properties.

In contrast, 2,3-dimethylpentane has a slightly less branched structure, which may result in slightly lower octane ratings. So, while both compounds are branched, the degree of branching and the resulting octane rating can differ.

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