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JAMB - Chemistry (1986 - No. 37)

In the solubility curve above, water at 98\(^0\)C is saturated with KCl and KCIO\(_3\). What is the percentage of KCl impurity in the crystals formed when the solution is cooled to 30\(^0\)C?

51.5
45.5
34.5
26.5

설명

From the graph, when you try to extrapolate the temperature to the solubility value of both KCl and KCIO\(_3\), we'll arrive at the following data:

    KCl   KClO\(_3\)

@ 98\(^0\)C

  55  55

@ 30\(^0\)C

  37  5
Difference  18  50

Total weight dissolved in 100g of water =  18 + 50 = 68g

% KCl impurity = \(\frac{weight of KCl}{Total weight}\times 100\)

  = \(\frac{18}{68}\times 100\)

  = 26.47

  = 26.5%

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