JEE MAIN - Chemistry (2006)

1
The standard enthalpy of formation $$\Delta _fH^o$$ at 298 K for methane, CH₄(g), is –74.8 kJ mol^–1. The additional information required to determine the average energy for C – H bond formation would be :
Απάντηση
(A)
the dissociation energy of H₂ and enthalpy of sublimation of carbon
2
An ideal gas is allowed to expand both reversibly and irreversibly in an isolated system. If T_i is the initial temperature and T_f is the final temperature, which of the following statements is correct?
Απάντηση
(A)
(T_f)_irrev > (T_f)_rev
3
The enthalpy changes for the following processes are listed below :

Cl₂(g) = 2Cl(g), 242.3 kJ mol^–1
I₂(g) = 2I(g), 151.0 kJ mol^–1
ICl(g) = I(g) + Cl(g), 211.3 kJ mol^–1
I₂(s) = I₂(g), 62.76 kJ mol^–1

Given that the standard states for iodine and chlorine are I₂(s) and Cl₂(g), the standard enthalpy of formation for ICl(g) is :
Απάντηση
(C)
+16.8 kJ mol^–1
4
($$\Delta H - \Delta U$$) for the formation of carbon monoxide (CO) from its elements at 298 K is : (R = 8.314 J K^–1 mol^–1)
Απάντηση
(B)
1238.78 J mol^–1
5
Phosphorus pentachloride dissociates as follows, in a closed reaction vessel
PCl₅ (g) $$\leftrightharpoons$$ PCl₃ (g) + Cl₂ (g)
If total pressure at equilibrium of the reaction mixture is P and degree of dissociation of PCl₅ is x, the partial pressure of PCl₃ will be
Απάντηση
(A)
$$\left( {{x \over {x + 1}}} \right)P$$
6
The equilibrium constant for the reaction
SO₃ (g) $$\leftrightharpoons$$ SO₂ (g) + $$1 \over 2$$ O₂ (g)
is K_c = 4.9 $$\times$$ 10^–2. The value of K_c for the reaction
2SO₂ (g) + O₂ (g) $$\leftrightharpoons$$ 2SO₃ (g) will be :
Απάντηση
(A)
416
7
Given the data at 25^oC,
Ag + I^- $$\to$$ AgI + e^- , E^o = 0.152 V
Ag $$\to$$ Ag⁺ + e^-, E^o = -0.800 V
What is the value of log K_sp for AgI? (2.303 RT/F = 0.059 V)
Απάντηση
(D)
–16.13
8
CH₃Br + Nu^- $$\to$$ CH₃ - Nu + Br^- The decreasing order of the rate of the above reaction with nucleophiles (Nu^–) A to D is
[Nu^– = (A) PhO^–, (B) AcO^–, (C) HO–, (D) CH₃O^–]
Απάντηση
(C)
D > C > A > B
9
The increasing order of stability of the following free radicals is
Απάντηση
(B)
$${(C{H_3})_2}\mathop C\limits^ \bullet H$$ < $${(C{H_3})_3}\mathop C\limits^ \bullet $$ < $${({C_6}{H_5})_2}\mathop C\limits^ \bullet H$$ < $${({C_6}{H_5})_3}\mathop C\limits^ \bullet$$
10
Increasing order of stability among the three main conformations (i.e. Eclipse, Anti, Gauche) of 2-fluoroethanol is
Απάντηση
(C)
Eclipse, Anti, Gauche
11
CH₃Br + Nu^- $$\to$$ CH₃ - Nu + Br^- The decreasing order of the rate of the above reaction with nucleophiles (Nu^–) A to D is
[Nu^– = (A) PhO^–, (B) AcO^–, (C) HO–, (D) CH₃O^–]
Απάντηση
(C)
D > C > A > B
12
How many EDTA (ethylenediaminetetraacetic acid) molecules are required to make an octahedral complex with a Ca²⁺ ion?
Απάντηση
(C)
One
13
Phenyl magnesium bromide reacts with methanol to give
Απάντηση
(B)
a mixture of benzene and Mg(OMe)Br
14
Fluorobenzene (C₆H₅F) can be synthesized in the laboratory
Απάντηση
(B)
from aniline by diazotisation followed by heating the diazonium salt with HBF₄
15
Reaction of trans-2-phenyl-1-bromocyclopentane on reaction with alcoholic KOH produces
Απάντηση
(D)
3-phenylcyclopentene
16
HBr reacts with CH₂ = CH – OCH₃ under anhydrous conditions at room temperature to give
Απάντηση
(D)
H₃C – CHBr – OCH₃
17
The term anomers of glucose refers to
Απάντηση
(D)
isomers of glucose that differ in configuration at carbon one (C-1)
18
The pyrimidine bases present in DNA are
Απάντηση
(C)
cytosine and thymine
19
In Fe(CO)₅, the Fe – C bond possesses :
Απάντηση
(B)
both $$\sigma$$ and π characters
20
The $$IUPAC$$ name of the compound shown below is :

Απάντηση
(A)
$$3$$-bromo - $$1$$-chlorocyclohexene
21

The alkene formed as a major product in the above elimination reaction is
Απάντηση
(B)
22
The structure of the major product formed in the following reaction

is
Απάντηση
(B)
23
The structure of the compound that gives a tribromo derivative on treatment with bromine water is
Απάντηση
(C)
24

The electrophile involved in the above reaction is
Απάντηση
(D)
25
Among the following the one that gives positives iodoform test upon reaction with $${I_2}$$ and $$NaOH$$ is
Απάντηση
(B)
$$PhCHOHC{H_3}$$
26
The correct order of increasing acid strength of the compounds

Απάντηση
(A)
$$D < A < B < C$$
27
A metal, $$M$$ forms chlorides in its $$+2$$ and $$+4$$ oxidation states. Which of the following statements about these chlorides is correct?
Απάντηση
(A)
$$MC{l_2}$$ is more ionic than $$MC{l_4}$$
28
Rate of a reaction can be expressed by Arrhenius equation as:
$$$k = A\,{e^{ - E/RT}}$$$ In this equation, E represents
Απάντηση
(A)
the energy above which all the colliding molecules will react
29
Among the following mixtures, dipole-dipole as the major interaction, is present in
Απάντηση
(B)
acetonitrile and acetone
30
18 g of glucose (C₆H₁₂O₆) is added to 178.2 g of water. The vapour pressure of water for this aqueous solution at 100^oC is
Απάντηση
(D)
752.40 Torr
31
The molar conductivities $$ \wedge _{NaOAc}^o$$ and $$ \wedge _{HCl}^o$$ and at infinite dilution in water at 25^oC are 91.0 and 426.2 Scm²/mol respectively. To calculate $$ \wedge _{HOAc}^o$$ , the additional value required is
Απάντηση
(D)
$$ \wedge _{NaCl}^o$$
32
Which of the following chemical reactions depicts the oxidizing behaviour of H₂SO₄?
Απάντηση
(C)
2HI + H₂SO₄ $$\to$$ I₂ + SO₂ + 2H₂O
33
Resistance of a conductivity cell filled with a solution of an electrolyte of concentration 0.1 M is 100$$\Omega $$. The conductivity of this solution is 1.29 S m^–1. Resistance of the same cell when filled with 0.2 M of the same solution is 520 $$\Omega $$, The molar conductivity of 0.02 M solution of the electrolyte will be
Απάντηση
(D)
12.4 $$\times$$ 10^–4 S m² mol^–1
34
A reaction was found to be second order with respect to the concentration of carbon monoxide. If the concentration of carbon monoxide is doubled, with everything else kept the same, the rate of reaction will
Απάντηση
(C)
increase by a factor of 4
35
In the transformation of $${}_{92}^{238}U$$ to $${}_{92}^{234}U$$, if one emission is an α-particle, what should be the other emission(s)?
Απάντηση
(A)
Two $$\beta^-$$
36
The following mechanism has been proposed for the reaction of NO with Br₂ to form NOBr:
NO(g) + Br₂ (g) $$\leftrightharpoons$$ NOBr₂ (g)
NOBr₂ (g) + NO (g) $$\to$$ 2NOBr (g)
If the second step is the rate determining step, the order of the reaction with respect to NO(g) is
Απάντηση
(D)
2
37
The increasing order of the first ionization enthalpies of the elements B, P, S and F (lowest first) is :
Απάντηση
(D)
B < S < P < F
38
Which of the following statements is true?
Απάντηση
(D)
HNO₃ is a stronger acid than HNO₂
39
The “spin-only” magnetic moment [in units of Bohr magneton, (µ_B)] of Ni²⁺ in aqueous solution would be : (Atomic number of Ni = 28)
Απάντηση
(A)
2.84
40
Lanthanoid contraction is caused due to :
Απάντηση
(D)
the imperfect shielding on outer electrons by 4f electrons from the nuclear charge
41
Nickel (Z = 28) combines with a uninegative monodentate ligand X^– to form a paramagnetic complex [NiX₄]²⁻ . The number of unpaired electron(s) in the nickel and geometry of this complex ion are, respectively
Απάντηση
(B)
two, tetrahedral
42
How many moles of magnesium phosphate Mg₃(PO₄)₂ will contain 0.25 mole of oxygen atoms?
Απάντηση
(D)
3.125 $$\times$$ 10^-2
43
Density of a 2.05M solution of acetic acid in water is 1.02 g/mL The molality of the solution is
Απάντηση
(A)
2.28 mol kg^-1
44
Uncertainty in the position of an electron (mass = 9.1 $$\times$$ 10^-31 kg) moving with a velocity 300 ms^-1, accurate upto 0.001% will be (h = 6.63 $$\times$$ 10^-34 Js)
Απάντηση
(A)
1.92 $$\times$$ 10^-2 m
45
Uncertainty in the position of an electron (mass = 9.1 $$\times$$ 10^-31 kg) moving with a velocity 300 ms^-1, accurate upto 0.001% will be (h = 6.63 $$\times$$ 10^-34 Js)
Απάντηση
(A)
1.92 $$\times$$ 10^-2 m
46
According to Bohr's theory, the angular momentum of an electron in 5^th orbit is
Απάντηση
(B)
2.5 $$h/\pi$$
47
Which of the following sets of ions represents a collection of isoelectronic species?
Απάντηση
(C)
K⁺, Cl^-, Ca²⁺, Sc³⁺
48
Following statements regarding the periodic trends of chemical reactivity of the alkali metals and the halogens are given. Which of these statements gives the correct picture?
Απάντηση
(D)
In alkali metals the reactivity increases but in the halogens it decreases with increase in atomic number down the group
49
Which of the following molecules/ions does not contain unpaired electrons?
Απάντηση
(A)
$$O_2^{2−} $$
50
In which of the following molecules/ions are all the bonds not equal?
Απάντηση
(C)
SF₄
51
The decreasing values of bond angles from NH₃ (106^o) to SbH₃ (91^o ) down group-15 of the periodic table is due to
Απάντηση
(C)
decreasing lp-bp repulsion